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Simultaneous Determination of 65 Polychlorinated Biphenyls,Polycyclic Aromatic Hydrocarbons and Organochlorine Pesticides in Marine Sediments by GC-MS with Accelerated Solvent Extraction |
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DOI:10.3969/j.issn.1004-4957.年份.月份 |
KeyWord:marine sediments polychlorinated biphenyls polycyclic aromatic hydrocarbons or ganochlorine pesticides simultaneous determination |
Author | Institution |
HE Xingliang1,2,3,XIA Ning1,2,ZHANG Yuanyuan2,WANG Jiangtao3 |
1.国土资源部海洋油气资源与环境地质重点实验室;2.青岛海洋地质研究所;3.中国海洋大学海洋化学理论与工程技术教育部重点实验室 |
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Abstract: |
A gas chromatography-mass spectrometry(GC-MS) coupled with accelerated solvent extraction(ASE) method was developed for the simultaneous determination of 28 polychlorinated biphenyls,16 polycyclic aromatic hydrocarbons and 21 organochlorine pesticides in marine sediments.The results indicated that the best simultaneous extraction temperature and time were 100 ℃ and 5 min,respectively.Under the optimal conditions,the analysis of 65 compounds were carried out with GC-MS.The calibration curves were linear in the range of 005-500 mg/L for PAHs with correlation coefficients(r2) of 0991-0999 and 50-5000 μg/L for PCBs and OCPs with r2 no less than 0996.The limits of detection of PCBs,PAHs and OCPs were in the range of 003-011,004-073,006-048 μg/kg,and the limits of quantitation were in the range of 011-035,012-242,018-161 μg/kg,respectively.The spiked recoveries ranged from 70% to 146% with RSDs(n=6) of 12%-173% for all the compounds.Through marine sediments standard reference materials,the method was proved to be effective and accurate,and could be applied in the simultaneous determination of 65 compounds in marine sediments. |
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