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Determination of Benzhexol Hydrochloride by Electrochemiluminescence in the Presence of Sodium Dodecyl Benzene Sulfonate |
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DOI:10.3969/j.issn.1004-4957.年份.月份 |
KeyWord:benzhexol hydrochloride sodium dodecyl benzene sulfonate(SDBS) Ru(bpy)2+3 electrochemiluminescence |
Author | Institution |
李利军,邓春燕,高文燕,吴美艳,胡大春,黄文艺,李彦清 |
1.广西工学院生物与化学工程系;2.广西大学化学与化学工程学院 |
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Abstract: |
In the presence of sodium dodecyl benzene sulfonate(SDBS),the electrochemical and electrochemiluminescence(ECL) characteristics of the Ru(bpy)2+3- benzhexol hydrochloride(BH) system at Au electrode were studied by ECL and cyclic voltammetric(CV) method.The results showed that the ECL intensity of Ru(bpy)2+3 at Au electrode was enhanced significantly in the presence of BH.In the presence of SDBS,the ECL intensity of Ru(bpy)2+3- benzhexol hydrochloride system was enhanced about 16 times.Based on this,a new electrochemiluminescence method was established for the determination of BH.Under the optimum condition,the enhanced ECL intensity had a good linear relationship with the concentration of BH in the range of 4.0×10-7-1.0×10-4 mol/L,with a detection limit of 1.11×10-9 mol/L.The RSD(n=10) of ECL intensities for the determinations of 1.0×10-5 mol/L BH were 3.2%.The recoveries for the samples were between 96% and 108% with RSD of 4.3%.With high selectivity and sensitivity,this proposed method was applied in the determination of BH in real sample with satisfactory results. |
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