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Determination of 11 Phenoxy Acid Herbicides in Fruits by Online GPC/GC-MS Method |
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DOI:10.3969/j.issn.1004-4957.年份.月份 |
KeyWord:online GPC/GC-MS phenoxy acid herbicides pesticide residues fruits |
Author | Institution |
张帆,付善良,施雅梅,李忠海,张莹,王美玲,颜鸿飞,黄志强 |
1.长沙环境保护职业技术学院;2.食品安全科学技术湖南省重点实验室,湖南省检验
检疫科学技术研究院;3.中南林业科技大学食品科学与工程学院;4.厦门出入境检验检疫局技术中心 |
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Abstract: |
An automated online gel chromatography/gas chromatography-mass spectrometry(GPC/GC-MS) method was established for the determination of 11 phenoxy acid herbicide residues in fruits.The sample was extracted with acetone-hexane and derivatived with butanol sulfuric acid,then the extract was purified by Florisil solid phase extraction column and analyzed by automated online GPC/GC-MS under selected ion monitoring(SIM) mode.The results indicated that the calibration curves of 11 pesticides were linear in the range of 0.01-1.0 mg/L ,with correlation coefficients of 0.998 7-0.999 9.The average recoveries of 11 phenoxy acid herbicide in fruits at spiked levels of 0.02-0.10 mg/kg ranged from 66%to 112% with relative standard deviations(RSDs) of 3.4%-11.5%.The method has high sensitivity for 11 phenoxy acid herbicides with quantitation limits of 7-10 μg/kg.The method was simple,rapid,sensitive and effective,and could meet the requirement for the simultanous determination of 11 pesticide residues in fruits. |
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