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Postsynthetic Covalent Modification of IRMOF-3 and Its Luminescence Properties |
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DOI:10.3969/j.issn.1004-4957.年份.月份 |
KeyWord:IRMOF-3 metal-organic frameworks post synthetic modification solid-fluorescence |
Author | Institution |
汪淑华,李鹏飞,王正仁,张宁 |
南昌大学化学系 |
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Abstract: |
An isoreticular metal-organic framework(IRMOF-3) was modified with salicylaldehyde(sal) by postsynthetic modification(PSM) method.The compound was metallated with M(acac)n(M=Mg,Zn,Pr,Ni) and the characteristics of the complex of IRMOF-3-Msal were investigated by solid-state fluorescence spectroscopy.The emission peaks of IRMOF-3-Znsal exhibited the maximum blue shifted behavior and stronger relative fluorescence intensity.The further research indicated the fluorescence variations of IRMOF-3-sal metallated with M(NO3)n were better than that with M(acac)n. |
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